The present method is used for the determination of total hardness of water in drinking water, ground water and surface water. Determination of total calcium and magnesium ion concentration. The hypothesis for this experiment was to determine if complexometric titration technique can identify the total hardness of water through mathematical means. Jul 23, 2019 06 determine the total hardness of a water sample using edta. May 31, 2016 on the other hand, permanent hardness is due to the presence of sulphates, chlorides and nitrates of calcium and magnesium as like cacl 2, caso 4, mgcl 2 and mgso 4 in water. Determination of the hardness of water water hardness designation. Indicator change colour slowly at the end point and thus titration should be performed slowly and carefully. Water hardness testing by complexometric determination of calcium. Water hardness can be measured using a titration with ethylenediaminetetraacetic acid edta.
Complexometric determination of water hardness lab essay. Hardness is defined as calcium and magnesium ion content. Experiment 1 estimation of hardness of water by edta method. This method, called a complexometric titration, is used to find the total calcium and magnesium content of milk, sea water and various solid materials. This application note also uses edta titration with a potentiometric determination of the equivalent.
Abstract the water hardness for unknown water sample number 40 was determined. Determination of hardness in water denver instrument. This lab will introduce you to the concept of complexometric titrations. Both the total hardness and the individual calcium and magnesium hardnesses will be measured. Add 6 drops of indicator and 3 ml of buffer solution. Water hardness can be readily determined by titration with the chelating agent greek. The calcium in the water will be measured by performing a titration with edta. Determination of the total hardness in tap water using.
The combined concentration of calcium and magnesium ions is. Application note determination of total hardness in water by automatic titration key words edta, complexometric, titrimetric, astm d1126, astm d511, iso 6059, sm 2340c, sm 3500ca, magnesium. Boil it to remove temporary hardness to about half of this volume and cool to room. To determine the total hardness of water with edta method initially an inorganic acid is added to convert temporary hardness into permanent hardness. Since edta is insoluble in water, the disodium salt of edta is taken for this experiment. At ph around 10 edta easily reacts with both calcium and. Before the endpoint of the titration, the solution is red because of the excess metal ion. Both the total hardness and the individual calcium and magnesium hardnesses will be. The classification of degree of water hardness according to the us geological survey is as follows. However, the modified starch is an organic matter its can be contaminates in water. Complexometric titration is one of the best ways of measuring total water hardness. To determine the hardness of a sample of water by using. A major application of edta titration is testing the hardness of water, for which the method described is an official one standard methods for the examination of water and wastewater, method. To determine the hardness of a sample of water by using edta to determine the concentration of calcium and magnesium ions.
When the water is boiled then, the bicarbonate of calcium and magnesium are change into nondissolve carbonate. Determination of total water hardness by complexometric titration. The competition of complexing agents for the same metal ion and the formation of colored metalion complexes is demonstrated with the use of an overhead projector. The hypothesis for this experiment was to determine if complexometric titration technique can identify the total hardness of.
Procedure for calculation of hardness of water by edta titration take a sample volume of 20ml v ml. With the use of disodium salt edta as the solution to chelate the metal impurities and the eriochrome black t indicator as the solution used to help. Ebt is the metal ion indicator used in the determination of hardness by complexometric titration with edta. The purpose of this experiment is to determine the total hardness of water at the universitys chemistry laboratory using a standardized titrant, ethylenediaminetetraacetic acid, by applying the principles of complexometric and displacement. Determination of total hardness of water hard and soft water. Determination of total hardness of water by complexonometric titration edta file. What effect will a brita filter have on water hardness.
With the use of disodium salt edta as the solution to chelate the metal impurities and the eriochrome black t indicator as the solution used to help visualize when the impurities were completely. Pdf determining the hardness of various water samples. Experiment 1 estimation of hardness of water by edta. Estimation of total, permanent and temporary hardness of. Complexometric titrations are generally run in order to determine divalent cations.
Determining total hardness in water by complexometric titration key concepts. There are 3 steps to determining the concentration of calcium and magnesium ions in hard water using the complexometric titration method with edta. Analyticalchemlab 8 lab report chem 3351 ttu studocu. The type of titration using edta and eriochrome black t explained above will be used to determine the level of calcium ions in parts per million.
Determination of permanent hardness of water by ohehners method theory. After the addition of calmagite indicator the solution required 21. The most important applications are the titration of calcium and magnesium for example for water hardness and the determination of nickel, zinc, copper and cobalt for the plating industry. C difference of the actual laboratory temperature from 20 degrees centigrade. Edta dissolved in water forms a colourless solution. Objective apply the concept of complexometric titration in the determination of total hardness in drinking water 3. Determination of total hardness of water by complexonometric. Determination of water hardness using complexometric titration you will use edta complexometric titration to determine the hardness of a sample of water brought from your home. Determination of hardness of water by edta method youtube. Calcium and magnesium salts dissolved in water cause water hardness. Using the indicator eriochrome black t, magnesium and calcium will be determined together. In this article, we are going to talk about the determination of hardness of water by edta titration method. Quantitative determination of total hardness in drinking. Determination of total water hardness by complexometric.
Titration using eriochrome black t as indicator determines total hardness. Hardness 2340edta titrimetric method 237 2340 hardness. Hard water contains multiply charged ions such as calcium, magnesium, and heavy metal ions, which replace sodium. The hardness may range from zero to hundreds of milligrams per liter, depending on the source and treatment to which the water has been subjected. Determining the total hardness in water using complexometric titration with edta tutorial suitable for chemistry students. Feb 04, 2012 quantitative determination of total hardness in drinking water by complexometric edta titration 1.
Determination of total hardness in water by automatic titration key words edta, complexometric, titrimetric, astm d1126, astm d511, iso 6059, sm 2340c, sm 3500ca, magnesium, orion 9720bnwp, orion star t930, orion star t940, titrator. The use of edta as a complexometric titrant for metal ions has been investigated in the past few. Determining total hardness in water chemistry tutorial. Determination of water hardness by complexometric titration.
Hardness of water has traditionally been determined by a complexometric titration with ethylene diaminetetraacetic acid edta. Water hardness can be readily determined by titration with the chelating agent. When the water is boiled then, the bicarbonate of calcium and magnesium are change into non. Water hardness is an expression for the sum of the calcium and magnesium cation concentration in a water sample. Determination of total hardness repeat the above titration method for sample hard water instead of standard hard water. Hard water requiring a considerable amount of soap to produce leather.
Quantitative determination of total hardness in drinking water by complexometric edta titration 1. Determination of permanent hardness of water hard and. Determination of total hardness of water the use of edta as a complexometric titrant for metal ions has been investigated in the past. Exp 5 gravimetric determination of nickel using dimethylglyoxime. Titrate the solutions with the titrant until the color changes from wine red to. Water hardness is a measure of the concentration of all the polyvalent cations dissolved in the water. This demonstration can be used to emphasize both the relevance of the relative values of formation constants in the complexation of metal cations and the applicability of complexometric titrations in quantitative chemical analysis.
Since edta is insoluble in water, the disodium salt of edta is. The end point of titration is indicated by a sharp colour change from wine red to blue. Determining total hardness in water by complexometric. A useful application of complexation titration is the determination of the amount of calcium and magnesium in water, that is, the hardness of water. Hardness of water measures the sum of calcium and magnesium ions present in the water. Experiment 8 determination of total hardness of water by complexometric titration lab instructorandrew cho william parnell 411 abstract. Determination of hardness of water by edta titration. Estimation of hardness of water by edta method 1 experiment 1 estimation of hardness of water by edta method introduction water hardness is the traditional measure of the capacity of water to precipitate soap. In most water samples, calcium and magnesium are the chief contributors to water hardness.
Hardness of water by edta titration introduction water hardness is a measure of the amount of hard water cations in water. Add 500 ml of distilled water to your largest beaker at least 600 ml. Determination of water hardness using complexometric titration. Jordan university of science and technology faculty of engineering civil engineering department ce 453 environmental lab determination of hardness of water experiment 5 student name. Total hardness refers to the combined hardness caused by bicarbonates, sulfates and chlorides of calcium and magnesium hamilton, 1971. When the hardness numerically is equal to or less than the sum of carbonate and bicarbonate alkalinity, all hardness is carbonate hardness and noncarbonate hardness is absent. The method uses a very large molecule called edta which forms a complex with calcium ions. The estimation of hardness is based on complexometric titration. Drinking water, process water, cooling water, boiler. Pdf chem 28 quantitative determination of total hardness. Stability constant of calcium complex is a little bit higher, so calcium reacts first, magnesium later. Jul 11, 2018 the modified starch had capable to reduced total hardness from 350.
Repeat the above titration method for sample hard water instead of standard hard water. Determination of hardness of water by edta titrimetric method aim to determine the total hardness of the given samples by edta titrimetric method. The determination of the total hardness of water is based on complexometric titration of calcium and magnesium. Soft 0 60 ppm caco3 equivalents moderately hard 61 120 ppm caco3 equivalents hard 121 180 ppm caco3 equivalents very hard 181 ppm caco3 equivalents complexometric titration is based on the formation of a complex ion. Determination of hardness of water by edta titration duration. The abovementioned standard lays down a titration with edta at ph 10. The most common such cations are calcium and magnesium, although iron, strontium, and manganese may contribute to water hardness. The standard way to express water hardness is in ppm.
Determination of hardness of water by edta titrationcomplexometric titration. Amount of total hardness present in the given water sample mgl viva questions. It can also be used to determine the total hardness of fresh water provided the solutions used are diluted. This method, called a complexometric titration, is used to find the calcium content of milk, the hardness of water and the amount of calcium carbonate in various solid materials. In this experiment, the hardness of an unknown water sample will be determined.
Hardness of water is determined by titrating with a standard solution of ethylene diamine tetra acetic acid edta which is a complexing agent. This dyestuff tends to polymerize in strongly acidic solutions to a. Determination of water hardness using complexometric. Water hardness testing by complexometric determination of. Eriochrome blacktebt is the metal ion indicator used in the determination of hardness by complexometric titration with edta. This volume must be subtracted from the total edta volume used in each. Chem 28 quantitative determination of total hardness in drinking water by complexometric edta titration part i. These hard water cations include calcium, magnesium, iron, zinc and the other polyvalent metal ions.
At ph around 10 edta easily reacts with both calcium and magnesium in the same molar ratio 1. Determination of the hardness of water one of the factors that establishes the quality of a water supply is its degree of hardness. Lab5 determination of hardness of water slideshare. Aug 30, 2017 to determine the total hardness of a water sample using edta. The present method is used for the determination of total hardness of water in drinking water, ground. These cations form insoluble salts with a reagent in soap, decreasing it s cleaning effectiveness. Calculate the hardness in terms of parts per million calcium carbonate. Determination of permanent hardness of water hard and soft. The modified starch had capable to reduced total hardness from 350. Background water hardness refers to the presence of calcium and magnesium salts in. At first, the water is boiled to remove temporary hardness. Scaling of hot water pipes, boilers and other house. Determination of the hardness of water water hardness.
Edta determination of total water hardness water hardness is an expression for the sum of the calcium and magnesium cation concentration in a water sample. Determination of hardness of water by edta titrimetric method. Determination of water hardness of filtered and unfiltered water using complexometric titration. Dilute 20ml of the sample in erlenmeyer flask to 40ml by adding 20ml of distilled water. Determination of permanent hardness take 100 ml of sample hard water in 250 ml beaker. Principle originally, the hardness of water was understood to be a measure of the capacity of water for precipitating soap. This will then be compared to a scale of water hardness to see how hard the water actually is. The causes of hardness of water is by multivalent metallic cations, which react with soap to form precipitates and with certain anions present in water to form scale the primary cations causing hardness are calcium, magnesium, strontium, ferrous ion, and manganous ions. Nov 10, 2015 lab5 determination of hardness of water 1.